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Compared to rayon, cotton fabric is easy to care for. Although it stretches and pills over time, cotton with a higher thread count will hold up much better than cotton with a cheap and loose weave. On the other hand, Rayon gets weak when wet and may get damaged under heat. Therefore it is suggested to dry clean the rayon fabric to retain its shiny and silky surface.
Any material is created through chemical treatment and then cooled, heated, or converted through additional chemicals. It would not be considered a “natural fiber”. So no matter what the product label says, rayon is still a synthetic fiber.